New heteroleptic iridium complexes having one biphenyl-2,2 '-diyl and two bipyridyl based ligands

Lee, Kyu Reon; Eum, Min-Sik; Chin, Chong Shik; Lee, Seung Chan; Kim, In June; Kim, Young Sik; Kim, Youngmee; Kim, Sung-Jin; Hur, Nam Hwi

doi:10.1039/b904016c

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New heteroleptic iridium complexes having one biphenyl-2,2 '-diyl and two bipyridyl based ligands

Lee, Kyu Reon;
Eum, Min-Sik;
Chin, Chong Shik;
Lee, Seung Chan;
Kim, In June;
외 4명

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초록

The structural and spectroscopic properties of new heteroleptic iridium complexes having a biphenyl and two bipyridyl based ligands are reported; DFT calculations reveal that the HOMO is composed of the biphenyl and iridium d orbitals while the LUMO is localized mainly on the two bipyridyl based ligands.

키워드

EXCITED-STATE PROPERTIES; PHOSPHORESCENT EMISSION; BLUE; MECHANISM

제목: New heteroleptic iridium complexes having one biphenyl-2,2 '-diyl and two bipyridyl based ligands

저자: Lee, Kyu Reon; Eum, Min-Sik; Chin, Chong Shik; Lee, Seung Chan; Kim, In June; Kim, Young Sik; Kim, Youngmee; Kim, Sung-Jin; Hur, Nam Hwi

DOI: 10.1039/b904016c

발행일: 2009

유형: Article

저널명: Dalton Transactions

호: 19

페이지: 3650 ~ 3652