Extraction of interface trap density by analyzing organohalide perovskite and metal contacts using device simulation

초록

We estimated the interface trap density by examining methylamine-lead-iodide (MALI, CH3NH3PbI3) and metal contacts. We analyzed experimental current-voltage curves from two MALI-based resistive memory devices, which are Au/MALI/indium-tin-oxide and Ag/MALI/Pt, using a device simulator. We obtained effective work functions (EWFs) for MALI/metal contacts by considering Fermi level pinning attributed to the interface states comprising metal-induced gap states (MIGSs) and interface traps. Through our theoretical consideration, we concluded that the interface trap density is about 10(15) eV(-1) cm(-2) at MALI/metal contacts because the low MIGS density of about 10(13) eV(-1) cm(-2) obtained from a theoretical equation makes little contribution to the interface state density of 10(15) eV(-1) cm(-2) obtained from the linear fitting between the metal work functions and the EWFs. (C) 2019 Author(s).

키워드